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Oligobisvelcraplex: Self-assembled linear oligomer by solvophobic pi-pi stacking interaction of bisvelcrands based on resorcin[4]arene
(Chemical Equation Presented) Bisvelcrand 3 based on resorcin[4]arene was obtained by a stepwise route, and the formation of oligobisvelcraplex 3 n by solvophobic pi-pi stacking interaction was observed. 1H NMR spectroscopic studies revealed that DeltaG ?pSeudorotation of oligobisvelcraplex 3n is 16.7 kcal mol-1 in C6D5NO2 solution. The pulsed field gradient spin-echo (PGSE) NMR experiment and VPO experiment showed that the number of aggregation (n) ranges from 7 to 10 in CHCl3 solution at 298 K. In high concentration, bisvelcrand 3 tends to form gels or fiber.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Safety of 2,3-Dichloroquinoxaline, you can also check out more blogs about2213-63-0
Reference£º
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N1365 | ChemSpider