One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, category: quinoxaline, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 2213-63-0, Name is 2,3-Dichloroquinoxaline, molecular formula is C8H4Cl2N2
1,10-Phenanthroline-dithiine iridium and ruthenium complexes: Synthesis, characterization and photocatalytic dihydrogen evolution
We report the synthesis and the spectroscopic and electrochemical properties of six mononuclear iridium(iii) and ruthenium(ii) complexes bearing S,S?-extended phenanthroline ligands. Starting from 5,6-dibromide-1,10-phenanthroline, the dithiine derivatives N,N?-1,10-phenanthrolinedithiino[2,3-b]quinoxaline and N,N?-1,10-phenanthrolinedithiino[2,3-b]benzene were prepared by primary N,N?-complexation of the dibromo derivative and subsequent nucleophilic substitution at the complex. The photoluminescence of the phenanthroline-dithiine containing complexes shows distinctively increased lifetimes for all Ir(iii) and Ru(ii) complexes. The activity of the series of Ir(iii) and Ru(ii) complexes as photosensitizers in visible-light photocatalytic water reduction is demonstrated by dihydrogen evolution with a [Fe3(CO)12] catalyst and triethylamine as a sacrificial donor.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. category: quinoxaline, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 2213-63-0, in my other articles.
Reference£º
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N1326 | ChemSpider