1448-87-9, Name is 2-Chloroquinoxaline, belongs to quinoxaline compound, is a common compound. Quality Control of 2-ChloroquinoxalineIn an article, once mentioned the new application about 1448-87-9.
Acetonitrile Derivatives as Carbonyl Synthons. One-Pot Preparation of Diheteroaryl Ketones via a Strategy of Sequential SNAr Substitution and Oxidation
The anion of 2-aryl acetonitrile derivatives reacted with a variety of heteroaryl chlorides or bromides in an SNAr manifold to afford intermediate anions which were susceptible to oxidation. The addition of sodium peroxide and aqueous NH4OAc solution effected oxidation to afford aryl heteroaryl ketones in good yields. Aryl acetonitrile derivatives are thus umpolung-type synthons of the corresponding aryl carbonyl functionality.
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Reference£º
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N729 | ChemSpider