A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 90-52-8, Name is 8-Amino-6-methoxyquinoline, molecular formula is C10H10N2O. In an article, author is Liu, Zhenghui,once mentioned of 90-52-8, HPLC of Formula: C10H10N2O.
Oxidative annulations via double C-H bond cleavages: Approach to quinoline derivatives
An approach to complicated quinoline derivatives catalyzed by rhodium catalytic system via oxidative annulations was proposed. A systematic exploration was completed. All kinds of reaction parameters were determined. And 55 kinds of target molecules were obtained with moderate to high yields. Combination of double oxidants made the conversion proceed smoothly. A clear reaction mechanism was put forward. Adjacent pi systems might provide assistance for realizing the activation of relatively unreactive C(5)-H of imidazole rings by forming five-membered metallacycle intermediates. In addition, scaled-up experiment verified the practical applicability.
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Reference:
Quinoline – Wikipedia,
,Quinoline | C9H7N – PubChem