In homogeneous catalysis, catalysts are in the same phase as the reactants. Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 90-52-8, Name is 8-Amino-6-methoxyquinoline, molecular formula is C10H10N2O, belongs to quinoxaline compound, is a common compound. In a patnet, author is Liu, Zhenghui, once mentioned the new application about 90-52-8, Product Details of 90-52-8.
Oxidative annulations via double C-H bond cleavages: Approach to quinoline derivatives
An approach to complicated quinoline derivatives catalyzed by rhodium catalytic system via oxidative annulations was proposed. A systematic exploration was completed. All kinds of reaction parameters were determined. And 55 kinds of target molecules were obtained with moderate to high yields. Combination of double oxidants made the conversion proceed smoothly. A clear reaction mechanism was put forward. Adjacent pi systems might provide assistance for realizing the activation of relatively unreactive C(5)-H of imidazole rings by forming five-membered metallacycle intermediates. In addition, scaled-up experiment verified the practical applicability.
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Reference:
Quinoline – Wikipedia,
,Quinoline | C9H7N – PubChem