The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. In an article, author is Jin, Songyang, once mentioned the application of 857890-39-2, Formula: C22H23ClN4O7S, Name is Lenvatinib Mesylate, molecular formula is C22H23ClN4O7S, molecular weight is 522.9586, MDL number is MFCD18633219, category is quinoxaline. Now introduce a scientific discovery about this category.
Phosphoric Acid Mediated Light-Induced Minisci C-H Alkylation of N-Heteroarenes
Herein, we report an environmentally-friendly light-induced Minisci alkylation of N-heteroarenes with a broad substrate scope using diphenyl phosphate as catalyst under metal- and photocatalyst-free conditions. The radical precursor redox-active esters (RAEs) were introduced as alkylating reagents for the functionalization of N-heteroarene derivatives including pyridine, quinoline, and isoquinoline. Mechanistic studies suggested that diphenyl phosphate played a key role via hydrogen bonding in the catalytic cycle.
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Reference:
Quinoline – Wikipedia,
,Quinoline | C9H7N – PubChem