Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. Related Products of 2213-63-0, In a article, mentioned the application of 2213-63-0, Name is 2,3-Dichloroquinoxaline, molecular formula is C8H4Cl2N2
Two new phi-conjugated 1, 3-dithiol-2-ylidene-containing ligands, 4, 5-[10, 40]dithiino[20, 30-b]quinoxaline-2-bis(2-pyridyl) methylene-1, 3-dithiole (L1) and 4, 5-bis(methylthio)-2-bis(2-pyridyl)methylene-1, 3-dithiole (L2), have been synthesized and characterized. Using L1, L2, or dimethyl 2-[di(pyridin-2-yl)methylene]-1, 3-dithiole-4, 5-dicarboxylate (L3) as the auxiliary ligand and [(Tp)Fe(CN)3]-or [(i-BuTp)Fe(CN)3]-[Tp = tris(pyrazolyl)borate; i-BuTp = 2-methylpropyltris(pyrazolyl)borate] as the building block, two rectangular-square Fe2Ni2 clusters [(Tp)Fe(CN)3-Ni(L1)2]2 · 2ClO4 · 6H2O (1) and [(i-BuTp)Fe(CN) 3Ni(L3)2]2 · 2ClO4 · 6H2O (2) and two trinuclear clusters [(Tp) 2Fe2(CN)6Ni(L2)2] · 8H2O (3) and [(Tp)2Fe2(CN) 6Co(L3)2] · 5H2O (4) have been prepared in parallel and structurally characterized. Complexes 1 and 2 show similar square structures, and weaker intermolecular phi-phi-stacking interactions through the pyrazolyl groups of the Tp-ligands are observed. 2D sheet structures are formed in complexes 3 and 4 through intermolecular phi-phi-stacking interactions. In 3, shorter S 3 3 3 S contacts further connect the 2D sheets to 3D supramolecular structures. Magnetic studies show intramolecular ferromagnetic coupling in complexes 1-4. Complexes 1 and 2 show obvious frequency dependencies in the alternating-current magnetic susceptibility data, indicating single-molecule-magnet behavior with effective spin-reversal barriers of 8.7 K for 1 and 13.5 K for 2, respectively.
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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N1498 | ChemSpider