New Advances in Chemical Research, May 2021. In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. Application of 15804-19-0, In a article, mentioned the application of 15804-19-0, Name is Quinoxaline-2,3(1H,4H)-dione, molecular formula is C8H6N2O2
o-Phenylenediamine 1 is condensed with oxalic acid using Phillips’ procedure to obtain quinoxaline-2, 3-dione 2. The latter on treatment with hydrazine hydrate gives the known 2-hydrazinoquinoxalin -3-one 3. Reaction of 3 with various acid chlorides (which were obtained from the corresponding carboxylic acids by reaction with thionyl chloride in the presence of catalytic amount of dimethyl formamide) in HMPA medium at 220C in one pot reaction yield the corresponding 1-substituted-4-dimethylamino[1, 2, 4]triazolo[4, 3-a]quinoxalines 4. This reaction has been shown to proceed through the intermediacy of 2-(N-acyl/aryl hydrazinoquinoxalin -3-one 5 and 1-substituted-4-oxo-[1, 2, 4] triazolo[4, 3-a]quinoxalines 6. An interesting observation here has been that 5 can be cyclised to 6 at a considerably lower temperature of 100C than the requisite 220C using catalytic amount of HCl.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 15804-19-0 is helpful to your research. Application of 15804-19-0
Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N342 | ChemSpider