Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 32717-95-6, is researched, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2Journal, Bulletin de la Societe Chimique de France called Organometallic chemistry. VI. Meerwein reaction. IV. Mechanistic aspects, Author is Al Adel, I.; Adeoti Salami, B.; Levisalles, J.; Rudler, H., the main research direction is Meerwein reaction mechanism; allyl alc Meerwein reaction; benzenediazonium Meerwein reaction; pentenol Meerwein reaction.HPLC of Formula: 32717-95-6.
The key step in the Meerwein reaction of p-ClC6H4N2+ salts in the presence of unsaturated compounds is formation of aryl radicals; complexation of the Cu(I) salt with the unsaturated compound plays only a minor role. Thus, treatment of RCuCl or R2CuBF4 (R = cyclooctadiene) with p-ClC6H4N2+X- (X = Cl, BF4) gives no Meerwein products. Similarly, treatment of CH2:CHCH2OH, which complexes easily with Cu, with p-ClC6H4N2+ and a Cu(I) catalyst gives only 5% of the Meerwein product p-ClC6H4CH2CHClCH2OH. On the other hand, the Meerwein reaction of CH2:CH(CH2)2CH2OH with p-ClC6H4N2+ gives the Meerwein product p-ClC6H4CH2CHCl(CH2)2CH2OH, I [via an aryl intermediate oxidized to a carbocation by Cu(I)], as well as p-ClC6H4N:NCH(CH2C6H4Cl-p)(CH2)2CH2OH and II.
From this literature《Organometallic chemistry. VI. Meerwein reaction. IV. Mechanistic aspects》,we know some information about this compound(32717-95-6)HPLC of Formula: 32717-95-6, but this is not all information, there are many literatures related to this compound(32717-95-6).
Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider