The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: (R)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine(SMILESS: COC(C=C1P(C2=CC=CC=C2)C3=CC=CC=C3)=NC(OC)=C1C4=C(OC)N=C(OC)C=C4P(C5=CC=CC=C5)C6=CC=CC=C6,cas:221012-82-4) is researched.Product Details of 75732-01-3. The article 《3,3′-Bipyridine, 4,4′-bis(diphenylphosphino)-2,2′,6,6′-tetramethoxy-, (3R)-; 3,3′-Bipyridine, 4,4′-bis(diphenylphosphino)-2,2′,6,6′-tetramethoxy-, (3S)-》 in relation to this compound, is published in e-EROS Encyclopedia of Reagents for Organic Synthesis. Let’s take a look at the latest research on this compound (cas:221012-82-4).
Properties and applications of 3,3′-bipyridine, 4,4′-bis(diphenylphosphino)-2,2′,6,6′-tetramethoxy-, (3R)-; 3,3′-bipyridine, 4,4′-bis(diphenylphosphino)-2,2′,6,6′-tetramethoxy-, (3S)-, a chiral biaryl bisphosphine ligands used for high activity and selectivity in catalytic hydrogenation of ketones, β-ketoesters, α,β-unsaturated carbonyl compounds, quinolines; transfer hydrogenation, Pauson-Khand-type reactions, carbonylation and other reductions are reviewed.
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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider