Related Products of 32717-95-6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Vibrational spectra of 1,5-cyclooctadiene, di-μ-chlorobis[(1,5-cyclooctadiene)rhodium(I)], di-μ-chlorobis[(1,5-cyclooctadiene)copper(I)] and bis(1,5-cyclooctadiene)copper(I) perchlorate. Author is Barna, Gabriel G.; Butler, Ian S..
The vibrational spectra of 1,5-cyclooctadiene (C8H12, COD) and the Rh(I) and Cu(I) complexes, [(COD)RhCl]2, [(COD)CuCl]2 and (COD)2CuClO4, were investigated. In the liquid state, COD exists in a C2v “”tub”” configuration; the same structure is apparently also preserved in the solid at -196°. The spectra of the dimeric complexes are in accord with the known D2h mol. symmetries and assignments for the ν(C:C), ν(M-Cl) and ν(M-olefin) vibrations are proposed accordingly. The spectra of (COD)2CuClO4 indicate the presence of a non-bonded olefinic group and a 3-coordinate structure is proposed for the (COD)2Cu+ ion.
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Reference:
Quinoxaline – Wikipedia,
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