The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 8-Hydroxyquinoline 1-oxide(SMILESS: OC1=CC=CC2=CC=C[N+]([O-])=C12,cas:1127-45-3) is researched.SDS of cas: 34941-92-9. The article 《Light-induced changes in the fluorescence yield of chlorophyll α in Anacystis nidulans II. Fast changes and the effect of photosynthetic inhibitors on both the fast and slow fluorescence induction》 in relation to this compound, is published in Plant and Cell Physiology. Let’s take a look at the latest research on this compound (cas:1127-45-3).
The intensity dependence and spectral variations during the fast transient of chlorophyll a fluorescence were analyzed in a blue-green alga, A. nidulans. A prolonged dark adaptation and relatively high intensity of exciting illumination were required to evoke DPS (dip-peak-quasi steady state) type fluorescence yield fluctuations in Anacystis. At low to moderate intensities of exciting light, the time for the development of P depended on light intensities, but for M (maximum level), this remained constant at these intensities. Fluorescence emission was heterogeneous during the induction period. The P and M levels were relatively enriched in short-wave length system II chlorophyll a emission compared to D and S levels. The fast DPS transient was affected by an electron transport cofactor (methyl viologen) and inhibitors (e.g., DCMU [3-(3,4-dichlorophenyl)-1,1-dimethylurea], NH2OH) in a manner suggesting that these changes are mostly related to the oxidation-reduction level of intermediates between the 2 photosystems. The slow SM changes in fluorescence yield paralleled O evolution and were resistant to various electron transport inhibitors (o-phenanthroline, 8-hydroxyquinoline 1-oxide, salicylaldoxime, DCMU, NH2OH, and antimycin a). It appears that in Anacystis a net electron transport-supported oxidation-reduction state of the quencher regulates only partially the development of the DPS transient of the fluorescence yield but the development of the slow fluorescence yield changes may not be regulated by these reactions. The slow rise in the yield may be induced by a structural modification of the thylakoid membrane.
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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider