Application In Synthesis of 8-Hydroxyquinoline 1-oxide. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 8-Hydroxyquinoline 1-oxide, is researched, Molecular C9H7NO2, CAS is 1127-45-3, about Oxidation of 1-naphthol and related phenols with hydrogen peroxide and potassium superoxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides in different reaction conditions. Author is Chauhan, S. M. S.; Kalra, Bhanu; Mohapatra, P. P..
Reaction of 1-naphthol and related phenols with hydrogen peroxide catalyzed by 5,10,15,20-tetra(pentafluorophenyl)porphyrinatoiron(III) chloride gives quinones and oxidative coupling products, whereas the reaction of naphthols with hydrogen peroxide catalyzed by 5,10,15,20-tetramesitylporphyrinatoiron(III) chloride gives the above products along with quinone epoxides in moderate yields. The reaction of quinone with potassium superoxide catalyzed by Me12TPPFe(III)Cl and p-MeOTPPFe(III)Cl give higher yields of quinone epoxides than the reaction of quinone with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides.
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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider