The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 1-(Bromomethyl)-4-ethylbenzene, is researched, Molecular C9H11Br, CAS is 57825-30-6, about Phenylboronic acid-catalyzed tandem construction of S-S and C-S bonds: a new method for the synthesis of benzyl disulfanylsulfone derivatives from S-benzyl thiosulfonates, the main research direction is benzyl disulfanylsulfone preparation metal free; thiosulfonate benzyl tandem dimerization sulfonylation phenylboronic acid catalyst.Application In Synthesis of 1-(Bromomethyl)-4-ethylbenzene.
A unique phenylboronic acid-catalyzed dimerization-sulfonylation of S-benzyl thiosulfonates has been disclosed. A metal-free tandem construction of S-S and C-S bonds is an operationally simple method to access a wide range of benzyl disulfanylsulfone derivatives I (Ar1 = C6H5, 4-ClC6H5, 1-naphthyl, etc.; Ar2 = C6H5, 4-MeOC6H5, 2-thienyl, etc.) in high to excellent yields. Moreover, the robustness of this tandem transformation has been demonstrated by gram-scale reactions, and a plausible mechanism is also proposed.
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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider