Extracurricular laboratory: Synthetic route of 57825-30-6

I hope my short article helps more people learn about this compound(1-(Bromomethyl)-4-ethylbenzene)Category: quinoxaline. Apart from the compound(57825-30-6), you can read my other articles to know other related compounds.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Photocatalyst- and transition-metal-free α-allylation of N-aryl tetrahydroisoquinolines mediated by visible light, published in 2020, which mentions a compound: 57825-30-6, Name is 1-(Bromomethyl)-4-ethylbenzene, Molecular C9H11Br, Category: quinoxaline.

A convenient and efficient α-allylation of N-aryl tetrahydroisoquinolines I (R = H, 4-Br, 3-Me, 4-Et, etc.) has been achieved. This transformation can be realized under only visible light irradiation without the aid of transition metals or photocatalysts. The mechanism involves a novel in situ-generated electron-donor-acceptor (EDA) complex between the N-aryl tetrahydroisoquinolines I and an allyl or a benzyl bromide R1Br (R1 = 2-methylprop-2-en-1-yl, prop-2-en-1-yl, benzyl, 1-phenylethyl, etc.). Irradiation with purple light triggered single-electron transfer (SET) from the N-aryl tetrahydroisoquinolines I to the allyl or benzyl bromide of the EDA complex, induces the formation of the corresponding allyl or benzyl radical and the subsequent radical-radical coupling. This approach represents the first example of a photocatalyst- and transition-metal-free α-allylic and benzylic functionalization of N-aryl tetrahydroisoquinolines I.

I hope my short article helps more people learn about this compound(1-(Bromomethyl)-4-ethylbenzene)Category: quinoxaline. Apart from the compound(57825-30-6), you can read my other articles to know other related compounds.

Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider