The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 8-Hydroxyquinoline 1-oxide(SMILESS: OC1=CC=CC2=CC=C[N+]([O-])=C12,cas:1127-45-3) is researched.COA of Formula: C9H7NO2. The article 《8-Hydroxyquinophthalone derivatives》 in relation to this compound, is published in Latvijas PSR Zinatnu Akademijas Vestis, Kimijas Serija. Let’s take a look at the latest research on this compound (cas:1127-45-3).
8-Acetoxyquinophthalone (I, R = Ac, X = H) (II) was prepared in 62% yield by reaction of 8-quinolinol oxide with 1,3-indandione in Ac2O. Analogously prepared was I (R = Ac, X = Cl) in 62% yield. Hydrolysis of the acetate gave the corresponding alcs. (I, R = H, (Cl). Treatment of II with SO2Cl2 gave indandione (III, X = H). Analogously III (X = C) was obtained.
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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider