Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 32717-95-6, is researched, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2Journal, Article, Organic Letters called Asymmetric [4 + 3] Annulations for Constructing Divergent Oxepane Frameworks via Cooperative Tertiary Amine/Transition Metal Catalysis, Author is Chen, Zhi; Chen, Zhi-Chao; Du, Wei; Chen, Ying-Chun, the main research direction is oxepane framework preparation enantioselective diastereoselective; indole vinyl carbonate amine metal catalyst annulation.SDS of cas: 32717-95-6.
Asym. [4+3] annulations between isatin-derived Morita-Baylis-Hillman carbonates and two types of vinyl carbonates synergistically catalyzed by tertiary amines and transition metals, through chemoselective assemblies of in situ formed allylic ylides and metal-containing 1,4-dipoles were reported. A range of oxepane frameworks I [R1 = H, 5-Me, 5-Br, etc.; R2 = Me, Et; R3 = Me, allyl, Bn, etc.] and II [X = CF, CCH3, NH, etc.] were generally constructed in moderate to good yields with high stereocontrol. Moreover, all four diastereomers for the products bearing vicinal stereocenters were accessible by tuning tertiary amine and metal catalysts.
This literature about this compound(32717-95-6)SDS of cas: 32717-95-6has given us a lot of inspiration, and I hope that the research on this compound(Chloro(1,5-cyclooctadiene)copper(I) dimer) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider