Extracurricular laboratory: Synthetic route of 221012-82-4

When you point to this article, it is believed that you are also very interested in this compound(221012-82-4)Electric Literature of C38H34N2O4P2 and due to space limitations, I can only present the most important information.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols, published in 2018, which mentions a compound: 221012-82-4, Name is (R)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine, Molecular C38H34N2O4P2, Electric Literature of C38H34N2O4P2.

The first nickel-catalyzed enantioselective allylic alkylation of lactone and lactam substrates to deliver α-quaternary lactones and lactams bearing an all-carbon quaternary stereocenter I [X = O, N-Bz, R1 = Me, Et; R2 = H, Ph, 2-furanyl, etc.] was reported. The reaction, which utilize a com. available chiral bisphosphine ligand, proceeded in good yield with a high level of enantioselectivity (up to 90% ee) on a range of unactivated allylic alcs. for both lactone and lactam nucleophiles. The utility of this method was further highlighted via a number of synthetically useful product transformations.

When you point to this article, it is believed that you are also very interested in this compound(221012-82-4)Electric Literature of C38H34N2O4P2 and due to space limitations, I can only present the most important information.

Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider