Inoue, Mami published the artcileInherently Chiral Cavitand Curvature: Diastereoselective Oxidation of Tethered Allylsilanes, Formula: C9H6Cl2N2, the main research area is chiral cavitand tethered allylsilane preparation stereoselective oxidation; epoxide chiral cavitand tethered silane preparation.
Syntheses of inwardly and outwardly directed allylsilanes those are tethered to new inherently chiral cavitands are described. Oxidized with mCPBA, these allylsilanes result in diastereomeric mixtures of epoxide mols. Thus, it enables the authors to have comparative study of cavitand-structure diastereoselectivity relation, which revealed that an inward allylsilane group flanked by a dibenzo[f, h]quinoxaline and two bridged methylene groups have the best chem. yield and diastereoselection.
European Journal of Organic Chemistry published new progress about Epoxidation, stereoselective. 39267-05-5 belongs to class quinoxaline, name is 2,3-Dichloro-6-methylquinoxaline, and the molecular formula is C9H6Cl2N2, Formula: C9H6Cl2N2.
Referemce:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider