Formula: C16H16Cl2Cu2. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Chemistry of copper(I) β-diketonate complexes. VI. Synthesis, characterization and chemical vapor deposition of 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione (fod) copper(I) (fod)CuL complexes and the solid state structure of (fod)Cu(PMe3). Author is Chi, K. M.; Corbitt, T. S.; Hampden-Smith, M. J.; Kodas, T. T.; Duesler, E. N..
A series of copper(I) compounds of the general formula (fod)CuL, where fod = 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione, and L = PMe3, PEt3, 1,5-cyclooctadiene (1,5-COD), vinyltrimethylsilane (VTMS), 2-butyne, bis(trimethylsilyl)acetylene (BTMSA), have been prepared by the reaction of Na[fod] with CuCl in the presence of the appropriate amount of the Lewis base, L. All the compounds were characterized by elemental anal., 1H, 13C, 19F, 31P and IR spectroscopies. The spectroscopic data are consistent with the chelation of the β-diketonate ligand through its oxygen atoms to the copper(I) center. The anal. data are consistent with the empirical formula (fod)CuL. One compound, (fod)CuPMe3, was characterized in the solid-state by single-crystal x-ray diffraction which confirmed the empirical formula and revealed the monomeric nature of this species in the solid state. The distorted trigonal planar coordination environment observed for this species is common to these species. The Cu-O distances are significantly different within the limits of error on the data possibly as a result of inductive effects of the different β-diketonate substituents. Hot- and cold-wall chem. vapor deposition experiments revealed that these species are generally not suitable as precursors for the deposition of copper due to their low thermal stability. While pure copper films could be deposited, as determined by Auger electron spectroscopy, from the compounds (fod)CuL, where L = PMe3, 2-butyne and BTMSA, heating the precursors to increase their vapor pressures resulted in significant thermal decomposition in the source reservoir. As a result, deposition rates of only 100 Å/min were achieved. No selectivity was observed on W vs. SiO2 substrates under the conditions employed. The other compounds, (fod)CuL, where L = 1,5-COD, VTMS, were too thermally unstable for CVD experiments
From this literature《Chemistry of copper(I) β-diketonate complexes. VI. Synthesis, characterization and chemical vapor deposition of 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione (fod) copper(I) (fod)CuL complexes and the solid state structure of (fod)Cu(PMe3)》,we know some information about this compound(32717-95-6)Formula: C16H16Cl2Cu2, but this is not all information, there are many literatures related to this compound(32717-95-6).
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