Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Diademane and structurally related compounds. II. Catalyzed rearrangements and hydrogenations.HPLC of Formula: 32717-95-6.
Cu and Ag compounds catalyzed the rearrangement of diademane (I) to triquinacene (II); Au and Rh compounds catalyzed the rearrangement of I to snoutene (III). Catalytic hydrogenation of I gave IV-IX; no adamantane was detected.
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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider