So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Qi, Zaojuan; Li, Weihe; Niu, Yanning; Benassi, Enrico; Qian, Bo researched the compound: 1-(Bromomethyl)-4-ethylbenzene( cas:57825-30-6 ).Related Products of 57825-30-6.They published the article 《A General Method for the Dibromination of Vicinal sp3 C-H Bonds Exploiting Weak Solvent-Substrate Noncovalent Interactions》 about this compound( cas:57825-30-6 ) in Organic Letters. Keywords: dibromoalkyl benzene preparation; arylethane dibromination. We’ll tell you more about this compound (cas:57825-30-6).
A general procedure of 1,2-dibromination of vicinal sp3 C-H bonds of arylethanes using N-bromosuccinimide as the bromide reagent without an external initiator was established. The modulation of the strength of the intermol. noncovalent interactions between the solvent and arylethane ethanes, quant. evaluated via quantum chem. calculations, allowed to circumvent the fact that arylethane ethane cannot be dibrominated through traditional methods. The mechanism was explored by both experiments and quantum chem. calculations, revealing a radical chain with HAA process.
There is still a lot of research devoted to this compound(SMILES：CCC1=CC=C(CBr)C=C1)Related Products of 57825-30-6, and with the development of science, more effects of this compound(57825-30-6) can be discovered.
Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider