The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer(SMILESS: C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5,cas:32717-95-6) is researched.Recommanded Product: 1-(Bromomethyl)-4-ethylbenzene. The article 《Catalytic properties of precious metal complexes: carbonylation of methanol to acetic acid in the presence of iridium compounds》 in relation to this compound, is published in Journal of Molecular Catalysis. Let’s take a look at the latest research on this compound (cas:32717-95-6).
No major difference was found between Rh- and Ir-catalyzed homogeneous carbonylation of MeOH to HOAc, using MeI as promoter. The dependence of the activity on the nature of the Ir based catalyst is greater than that of th Rh-based catalyst, and the maximum activity occurs at different conditions. Rh(CO)2I2- and Ir(CO)2I2- are the catalytic species in these reactions and the Ir complexes are the best catalysts of all the Pt metal complexes. The mechanism of the reaction is discussed.
This literature about this compound(32717-95-6)Electric Literature of C16H16Cl2Cu2has given us a lot of inspiration, and I hope that the research on this compound(Chloro(1,5-cyclooctadiene)copper(I) dimer) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider