Vadagaonkar, Kamlesh S. published the artcileI2 catalyzed tandem protocol for synthesis of quinoxalines via sp3, sp2 and sp C-H functionalization, Recommanded Product: 2-(Thiophen-2-yl)quinoxaline, the main research area is ethylenearene phenylenediamine iodine tandem reaction quinoxaline preparation green chem; ethylarene phenylenediamine iodine tandem reaction quinoxaline preparation green chem; ethynearene phenylenediamine iodine tandem reaction quinoxaline preparation green chem.
One-pot, atom-economic synthesis of quinoxalines was achieved through generation of arylglyoxal from easily available ethylarenes, ethylenearenes and ethynearenes, and subsequent condensation with o-phenylenediamines. Catalytic I2 with tert-Bu hydroperoxide (TBHP) as an oxidant in DMSO was the system of choice for the domino reaction involving C-H functionalization/oxidative cyclization. The metal-free, mechanistically distinct and functional group tolerant tandem approach could be a powerful complement to traditional approaches for the synthesis of quinoxalines.
RSC Advances published new progress about Alkylarenes Role: RCT (Reactant), RACT (Reactant or Reagent). 40353-41-1 belongs to class quinoxaline, name is 2-(Thiophen-2-yl)quinoxaline, and the molecular formula is C12H8N2S, Recommanded Product: 2-(Thiophen-2-yl)quinoxaline.
Referemce:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider