Category: 1448-87-9

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Pyrrolopyrrole cyanine (PPCy) dyes are presented as a novel class of near-infrared (NIR) chromophores, which are synthesized in a condensation reaction of diketopyrrolopyr-role with heteroarylacetonitrile compounds. Their optical properties are marked by strong and narrow-band NIR absorptions. Complexation prod-ucts with BF2 and BPh2 show strong NIR fluorescence and hardly any ab-sorption in the visible range. We syn-thesized a series of new PPCys that differ only in the heterocyclic peripheral groups of the chromophore. With this strategy, the absorption spectra can be tuned between 684 and 864 nm, while high fluorescence quantum yields are maintained. The influence of the heterocycle on the optical properties of the dyes is discussed.

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N582 | ChemSpider

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A series of 4-substituted quinazolines and related compounds have been prepared and evaluated for their ability to inhibit the tyrosine kinase activity of the epidermal growth factor receptor on a phospholipase C-gamma1- derived substrate. The results show a narrow structure-activity relationship (SAR) for the basic ring system, with quinazoline being the preferred chromophore and benzylamino and anilino the preferred side chains. In the 4- anilino series, substitution on the 3-position of the phenyl ring with small lipophilic electron-withdrawing groups provided analogues with enhanced potency. Two series of compounds [4-(phenylmethyl)amino and 4-(3- bromophenyl)amino] were studied to determine SARs for quinazoline substituents. In the more active 4-(3-bromophenyl)amino series, electron- donating groups (NH2, OMe) at the 6- or 7-position increased activity, in a pattern consistent with a requirement for high electron density in the vicinity of the 8-position of the quinazoline ring. The 6,7-dimethoxy derivatives were the most effective in both series, with the 4-(3- bromophenyl)amino derivative (3) having an IC50 of 0.029 nM, making it by far the most potent reported inhibitor of the tyrosine kinase activity of the epidermal growth factor receptor enzyme.

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N669 | ChemSpider

Electric Literature of 1448-87-9, New Advances in Chemical Research in 2021. The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 1448-87-9, Name is 2-Chloroquinoxaline, molecular formula is C8H5ClN2. In a article，once mentioned of 1448-87-9

Compounds of formula (I) STR1 wherein R1, R2, R3, R4 and R5 are independently hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, alkylcycloalkyl, halogen, haloalkyl, alkoxy, alkenoxy, alkoxyalkyl, haloalkoxy, alkylthio, cyano, nitro, amino, NR7 R8, hydroxy, acylamino, –CO2 R6, phenyl, phenoxy, benzyl or benzyloxy, the phenyl group or phenyl moiety of the benzyl group being optionally substituted; or R2 and R3 when taken together form a 5- or 6-membered ring; R6 and R8 are hydrogen or C1-4 alkyl; R7 is C1-4 alkyl; and n is 0, 1 or 2: and compositions thereof, are useful for killing or controlling nematodes.

A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1448-87-9

Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N472 | ChemSpider

Application of 1448-87-9, New research progress on 1448-87-9 in 2021. Chemistry is a science major with cience and engineering. The main research directions are chemical synthesis, preparation and modification of special coatings, and research on the structure and performance of functional materials.1448-87-9, Name is 2-Chloroquinoxaline, molecular formula is C8H5ClN2. In a article，once mentioned of 1448-87-9

A mild and efficient alpha-heteroarylation of simple esters and amides was developed via nucleophilic aromatic substitution. The choice of NaHMDS in toluene gave the best results. A tandem alpha-heteroarylation and hydroxylation protocol using air as the oxidant afforded tertiary alcohols in good yields.

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N684 | ChemSpider

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The anti-quorum and DNA cleaving agent is directed to a ruthenium complex formulated from dichloro-(eta6-p-cymene) ruthenium(II) dimer and 2-chloroquinoxaline, the complex having the formula: The reaction cleaves the dimer, leaving a half-sandwich ruthenium complex with an eta6 coordination bond to the arene ligand and an Ru?N bond attaching the chloroquinoxaline to the ruthenium complex. The agent has an anti-quorum sensing effect on bacteria, inhibiting the formation of biofilm and inhibiting bacterial virulence. The agent also binds to DNA and may cleave the DNA, e.g., at the N7 base pair of guanine, due to a hydrolytic mechanism, suggesting potential use as an anticancer or antitumor agent.

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Quinoxaline – Wikipedia,
Quinoxaline | C8H6N479 | ChemSpider

New Advances in Chemical Research, May 2021. In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Reference of 1448-87-9, We’ll be discussing some of the latest developments in chemical about CAS: 1448-87-9, name is 2-Chloroquinoxaline. In an article，Which mentioned a new discovery about 1448-87-9

We report the synthesis of 2-(anthracen-9-yl)-1H-inden-3-yl dicyclohexylphosphine and its use in palladium-catalyzed borylation/Suzuki-Miyaura cross-coupling reaction to prepare a variety of symmetrical and unsymmetrical biaryl compounds in excellent yield. This journal is

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N551 | ChemSpider

New Advances in Chemical Research, May 2021. In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. Application In Synthesis of 2-Chloroquinoxaline, In a article, mentioned the application of 1448-87-9, Name is 2-Chloroquinoxaline, molecular formula is C8H5ClN2

Chlorination with equimolar POCl3 can be efficiently achieved not only for hydroxypyrimidines, but also for many other substrates such as 2-hydroxy-pyridines,-quinoxalines, or even-amides. The procedure is solvent-free and involves heating in a sealed reactor at high temperatures using one equivalent of pyridine as base. It is suitable for large scale (multigram) batch preparations.

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N713 | ChemSpider

New Advances in Chemical Research, May 2021. In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Reference of 1448-87-9, We’ll be discussing some of the latest developments in chemical about CAS: 1448-87-9, name is 2-Chloroquinoxaline. In an article，Which mentioned a new discovery about 1448-87-9

Two cobalt complexes, 5 and 7, both containing 11,11a-dihydropyrano[2,3-b]quinoxaline nuclei, were synthesised as model substances for the molybdenum cofactor of the oxomolybdoenzymes. The organic proligands for the ene-1,2-dithiolates, from which these complexes were formed, were 1,3-dithiol-2-ones, the dianionic ligands being liberated by reaction with caesium hydroxide. The pyran ring in the tetracyclic 1,3-dithiol-2-one proligands, 4b and 6, was formed by ring closure of the side-chain alcohol in 4-(1-hydroxyalkyl)-5-(quinoxalin-2-yl)-1,3-dithiol-2-one onto an aromatic quinoxaline via reaction with a chloroformate, generating 6-alkyloxycarbonyl-2-oxo-5a,6-dihydro-4H-[1,3]dithiolo[4′,5′:4,5]pyrano[2,3-b]quinoxalines which were then reduced with cyanoborohydride to give 6-alkyloxycarbonyl-5a,6,11,11a-tetrahydro-2-oxo-4H-[1,3]dithio[4′,5′:4,5]pyrano[2,3-b]quinoxalines – the proligands.

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N536 | ChemSpider

New Advances in Chemical Research, May 2021. The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry.Application In Synthesis of 2-Chloroquinoxaline, In a article, mentioned the application of 1448-87-9, Name is 2-Chloroquinoxaline, molecular formula is C8H5ClN2

The invention discloses a quinoxaline-containing 1, 4 – pentadiene – 3 – ketone derivatives, preparation method and application, the general formula (I) are as follows: Wherein R1 Is phenyl, substituted phenyl or substituted aryl heterocyclyl; R is in the quinoxaline structure 5, 6, 7 or 8 position containing more than one hydrogen atom, methoxy, nitro, methyl, trifluoromethyl or halogen atom. The compounds of the invention to liver cancer SMMC – 7721 cell has excellent inhibitory activity, and exhibits a high anti-tumor activity, can be used as potential anti-tumor pharmaceutical use. (by machine translation)

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N468 | ChemSpider

New Advances in Chemical Research, May 2021. The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates. Synthetic Route of 1448-87-9, We’ll be discussing some of the latest developments in chemical about CAS: 1448-87-9, name is 2-Chloroquinoxaline. In an article，Which mentioned a new discovery about 1448-87-9

A compound represented by general formula (I):A-B-D or a pharmacologically acceptable salt thereof.

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Reference：
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N480 | ChemSpider