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A series of D-(pi)-A?-pi-A featured organic dyes with different numbers of 3,4-ethylenedioxythiophene (EDOT) bridges and different anchoring groups, i.e., cyanoacrylic acid or rhodanine-3-acetic acid, have been designed and synthesized for application in quasi-solid-state dye-sensitized solar cells (DSSCs). The absorption, electrochemical and photovoltaic properties are systematically investigated. Upon the incorporation of an auxiliary EDOT unit into sensitizers FNE60 and FNE61 with D-A?-pi-A configuration, sensitizers FNE62 and FNE63 with D-pi-A?-pi-A configuration exhibit much broader absorption spectra, which is beneficial to the light-harvesting capability and photocurrent generation. When the cyanoacrylic acid group in sensitizers FNE60 and FNE62 is replaced by a much stronger electron-withdrawing group, rhodanine-3-acetic acid, strengthened intramolecular charge transfer interactions are realized, which results in the significantly bathochromically shifted maximum absorption wavelengths for sensitizers FNE61 and FNE63. However, the methylene group in the rhodanine-3-acetic acid unit interrupts the LUMO delocalization on the anchoring group in sensitizers FNE61 and FNE63, as revealed by theoretical calculation, which may result in less effective electron injection from the LUMO to the conduction band of the titania semiconductor. Consequently, the quasi-solid-state DSSC based on FNE62 exhibits a highest power conversion efficiency of 8.2%, which illustrates good long-term stability after continuous light soaking for 1000 h.

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By replacing the central thiophene unit of an anionic pentameric oligothiophene with other heterocyclic moities, a palette of pentameric thiophene-based ligands with distinct fluorescent properties were synthesized. All ligands displayed superior selectivity towards recombinant amyloid fibrils as well as disease-associated protein aggregates in tissue sections.

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Four D-A-pi-A motif organic sensitizers (IQ9, IQ10, IQ11 and IQ12) in the absence or presence of thiophene substituents grafted onto the auxiliary acceptor of a quinoxaline unit have been developed for dye sensitized solar cells (DSSCs). Upon changing the pi-linker from benzene to thiophene, the photocurrent (Jsc) of IQ10 increases around 2-fold, and the photovoltage (Voc) decreases by 52 mV compared to that of IQ9. It is attributed to the fact that compared with the benzene linker, the thiophene conjugated bridge in dye IQ10 induces a small twist in the molecular planarity, thus resulting in the high light-harvesting capability (beneficial to Jsc) and high charge recombination (unbeneficial to Voc). To prevent this “trade-off” effect between photocurrent and photovoltage, the building block of 2,3-dithienylquinoxaline as an auxiliary unit is specifically incorporated, which brings forth several advantages such as distinctly extending the light-harvesting region, increasing molar absorption coefficients, and blocking the dye self-aggregation to reduce charge recombination. Remarkably, dye IQ12 exhibits a beneficial balance between Jsc (17.97 mA cm-2) and Voc (715 mV), along with a promising photovoltaic efficiency of 8.76%, much better than the corresponding dyes IQ9 (2.91%), IQ10 (7.75%) and IQ11 (6.56%). As demonstrated, the two twisted thiophene groups grafted onto the quinoxaline unit facilitate the resulting compact sensitizer layer to effectively overcome the charge recombination drawbacks in Voc arising from the thiophene pi-bridge linker, providing a rational molecular engineering to pursue the synergistic enhancement in the photocurrent and photovoltage for highly efficient organic sensitizers.

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Electric Literature of 148231-12-3, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 148231-12-3, molcular formula is C8H4Br2N2, introducing its new discovery.

A new simple and efficient methodology for reductive sulfur extrusion from 2,1,3-benzothiadiazole compounds has been developed using NaBH4 in the presence of catalytic amounts of CoCl2·6H2O (1 mol %). This method is an efficient alternative for the generation of various 1,4-disubstituted-2,3-diaminobenzene derivatives from 4,7-disubstituted-2,1,3- benzothiadiazoles. The diamines can be easily converted into 4,7-disubstituted-quinoxaline compounds by simple reaction with glyoxal-sodium bisulfite.

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Related Products of 148231-12-3, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Review, and a compound is mentioned, 148231-12-3, 5,8-Dibromoquinoxaline, introducing its new discovery.

The quinoxaline derivatives are beneficial compounds because of their various medicinal and industrial applications. They are well-known for application in organic light emitting devices, polymers and pharmaceutical agents. The quinoxaline-containing polymers are applicable in optical devices due to their thermal stability and low band gap. There are many reported procedures for the synthesis of bis- and polyquinoxalines and quinoxaline-containing macrocycles. The quinoxaline-based compounds as fascinating structures are important subjects of interest in either basic or applied sciences. This review summarizes the latest progresses related to the quinoxalines, quinoxaline-containing macrocycles, and bis- and poly quinoxalines, including the synthesis, functionalization and modification methods and applications of these compounds.

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A new neutral state green polymer, poly (2,3-bis(4-tert-butylphenyl)-5,8-di(1H-pyrrol-2-yl) quinoxaline) (PTBPPQ) was synthesized and its potential use as an electrochromic material was investigated. Spectroelectrochemistry studies showed that polymer reveals two distinct absorption bands as expected for a donor-acceptor type polymer, at 408 and 745 nm. In addition, polymer has excellent switching properties with satisfactory optical contrasts and very short switching times. Outstanding optical contrast in the NIR region and stability make this polymer a great candidate for many applications. It should be noted that PTBPPQ is one of the few examples of neutral state green polymeric materials with superior switching properties. Hence, PTBPPQ can be used as a green polymeric material for display technologies.

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Band-gap engineering of donor – Acceptor-substituted pi-conjugated polymers

Three series of alternating donor- acceptor-substituted co-oligomers (with different chain lengths) have been prepared by application of the Pd-catalyzed Stille coupling methodology. They contain pyrrole or thiophene as the electron-rich unit and quinoxaline or 2,1,3-benzothiadiazole as the electron-deficient unit. The trimethylstannyl group is always located on the electron-rich unit, whereas the bromo substituent is always located on the electron-deficient one. The tBoc-protecting group is used in the synthesis of the pyrrole-containing oligomers. The incremental bathochromic shift of lambda(max) upon chain elongation of the three series of oligomers is less than that of the homooligomers of thiophene and pyrrole; this decrease is caused by a diminished dispersion of the LUMO level upon chain elongation. This conclusion was drawn after comparing the oxidation and reduction behavior of the thiophene/benzothiadiazote co-oligomers with that of thiophene oligomers. The incremental bathochromic shift is similar for all three series of oligomers and is used as a tool in the band-gap engineering of donor- acceptor-substituted pi-conjugated polymers.

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Two-component gel of a D-pi-A-pi-D carbazole donor and a fullerene acceptor

A D-pi-A-pi-D carbazole derivative (PCQ) with a quinoxaline moiety was designed and synthesized. Its photophysical properties in solution were studied. Moreover, PCQ was found to be a highly efficient gelator toward various apolar and polar organic solvents with the critical gelation concentrations (CGCs) as low as 0.06 wt/vol%. Spectral studies and molecular dynamic stimulation revealed that the intermolecular H-bonds and pi-pi stacking interactions might be responsible for guiding the self-assembly processes and the gel formation. Interestingly, PCQ could construct two-component gel with fullerene derivative driven by intermolecular hydrogen bonds. Moreover, the two-component gel film could generate photocurrent under light irradiation, indicating photo-induced electron transfer from the PCQ aggregate to the fullerene derivative.

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Synthesis, Properties, and Reactivity of Bis-BN Phenanthrenes: Stepwise Bromination of the Main Scaffold

Two bis-BN phenanthrenes have been synthesized. Their photophysical properties are different from those of the reported mono-BN phenanthrenes. Moreover, the stepwise bromination of bis-BN phenanthrene 8 gave a series of brominated bis-BN phenanthrenes, with all of the mono-, di-, tri-, and tetrabrominated bis-BN phenanthrenes being successfully isolated and characterized. In addition, preliminary results showed that mono- and dibrominated species can be further functionalized by cross-coupling reactions.

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AMINE COMPOUND AND ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME

An amine-based compound having a specific structure and an organic electroluminescence device which comprises at least one layer comprising at least a light emitting layer and is disposed between a cathode and an anode, wherein at least one layer in the organic thin film layer comprises the amine-based compound singly or as a component of a mixture. The organic electroluminescence device exhibits an excellent balance in physical properties such as a small ionization potential, a great band gap energy, a great efficiency of injection and a great mobility and excellent heat resistance and current efficiency due to the amine-based compound.

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Quinoxaline – Wikipedia,
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