Extracurricular laboratory:new discovery of 2,6-Dichloroquinoxaline

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An easy, efficient ptc-mediated synthesis of 2-substituted-6-chloroquinoxalines and antibacterial activity

An easy and efficient synthetic protocol has been developed for the synthesis of 2-substituted-6-Chloro-quinoxalines by the reaction of 2,6-Dichloroquinoxaline with different alcohols, thiols and amine using Tri Ethyl Benzyl Ammonium Chloride (TEBAC). The newly synthesized compounds characterized by spectral data such as IR,1HNMR,13CNMR and mass spectrometry. The compounds were screened for their in vitro antibacterial activity against four different organisms, resulted in the compounds showed good antibacterial activities.

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Antitumor compositions and methods of treatment

This invention provides certain sulfonamidoquinoxaline derivatives and methods for using them in the treatment of susceptible neoplasms in mammals. Also provided are certain novel pharmaceutical formulations employing these sulfonamidoquinoxaline derivatives, in combination with a carrier, diluent or excipient.

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4-quinoxalinyloxyphenoxyalkylinitrile herbicides

Herbicidal methods utilizing compounds having the structure STR1 wherein: n is 0, 1, 2, or 3; R is H or alkyl; and R1 is halogen, nitro, methyl, halomethyl, methoxy, halomethoxy or ethoxy are disclosed which control the growth of undesirable weeds but are substantially innocuous to corn. Herbicidal compositions comprising the compounds and a carrier are also disclosed.

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A new application about 2,6-Dichloroquinoxaline

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THE SYNTHESES OF NOVEL 2-(2-QUINOXALINYL)PYRIDAZIN-3(2H)-ONES

The first syntheses of 4-chloro-2-(2-quinoxalinyl)-pyridazin-3(2H)-one derivatives are reported.They could be synthesized from 2-hydrazinoquinoxaline derivatives as starting materials.

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Archives for Chemistry Experiments of 2,6-Dichloroquinoxaline

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Tetrahydroisoquinoline – 2 – base aryloxy phenoxy alkyl ketone compound and use thereof (by machine translation)

The invention discloses tetrahydroisoquinoline – 2 – base aryloxy phenoxy alkyl ketone compound and its application, the chemical structural formula shown in formula I or II: In the formula, R1 , R2 , R3 , R4 Are independently hydrogen or C1 – C3 C alkyl or1 – C3 Halogenated alkyl in any one of; X is nitrogen or carbon; X1 , X2 , X3 , X4 , X5 Are respectively hydrogen either fluorine or chlorine either bromine or iodine or trifluoromethyl or cyano or nitro in any one of the. The invention also relates to a composition containing the above-mentioned compound and tetrahydroisoquinoline – 2 – base aryloxy phenoxy cyclic amine in agricultural herbicide application, some compounds have herbicidal activity of very high, in the amount of 5 g/mu can be obtained under a very good control effect. (by machine translation)

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Reference of 18671-97-1, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.18671-97-1, Name is 2,6-Dichloroquinoxaline, molecular formula is C8H4Cl2N2. In a Article£¬once mentioned of 18671-97-1

FACILE SYNTHESIS AND HERBICIDAL ACTIVITIES OF NOVEL FLUOROQUINOXALINES

The synthesis of new 2-fluoro-, 3-fluoro- and 2,3-difluoroquinoxalines by nucleophilic substitution with cesium fluoride as coupled with 18-crown-6 and their herbicidal activities are described.

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Process for preparing 6-halo-2-chloroquinoxaline

A process for the preparation of 2-chloro-6-haloquinoxaline compounds from the corresponding 4-halo-2-nitroaniline utilizing four reaction steps with generally compatible solvents and reagents with volatile by-products to minimize the isolation and purification of intermediates has been developed.

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thick mixed oxygen radical phenoxy carboxylic acid derivatives and use thereof (by machine translation)

The invention discloses thick mixed oxygen radical phenoxy carboxylic acid derivatives and their herbicidal activity, the chemical structural formula shown in formula I: In the formula, R1 , R2 , R3 , R4 , R5 , R6 C is hydrogen or1 – C3 C alkyl or1 – C3 Halogenated alkyl in any one of; X is – N=CH – or oxygen; Y is nitrogen or oxygen; X1 For hydrogen either fluorine or chlorine either bromine or iodine or trifluoromethyl or cyano or nitro in any one of the. The invention also relates to a composition containing the above-mentioned compound and thick mixed oxygen radical phenoxy carboxylic acid derivatives in agricultural herbicide application, some compounds have herbicidal activity of very high, in the amount of 5 g/mu can be obtained under a very good control effect. (by machine translation)

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Extended knowledge of 18671-97-1

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ELECTROCHROMIC COMPOUND, ELECTROCHROMIC COMPOSITION, AND DISPLAY ELEMENT

To provide an electrochromic compound, represented by the following general formula (I): General Formula (I) where X1, X2, X3, X4, X5, X6, X7 and X8 are each independently a hydrogen atom or a monovalent substituent; R1 and R2 are each independently a monovalent substituent; A- and B- are each independently a monovalent anion; and Y is represented by the following general formula (II) or (III): General Formula (II) General Formula (III) where X9, X10, X11, X12, X13, X14, X15, X16, X17, and X18 are each independently a hydrogen atom or a monovalent substituent.

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A method for producing quizalofop-P-ethyl environment-friendly process (by machine translation)

The present invention relates to a method for producing quizalofop-P-ethyl environment-friendly process, characterized in that the first hydroquinone with sodium hydroxide reaction to prepare the sodium salt of hydroquinone, with 2, 6 – dichloro quinozaline reaction, to obtain 4 – (6 – chloro – 2 kuikui oh linlin oxygen radical) phenol, then with paratoluene sulfonic acid ethyl lactate reaction to obtain the quizalofop-P-ethyl, herbicide then the grease of the alkaline hydrolysis, acidification, recovery 6 – chloro – 2 – hydroxy-quinoxaline. The synthesis process is advantageous in that the organic solvent in the reaction and post-processing, the system reduces the response of the alkaline, avoids the strong alkaline aqueous phase reactions the drawback of easy to produce impurities, reduces the raw material 2, 6 – dichloro quinozaline hydrolysis, so that the 4 – (6 – chloro – 2 kuikui oh linlin oxygen radical) to the phenol content of 98% or more, the yield of 92% or more, the recovery of the herbicide of the grease in the 6 – chloro – 2 – hydroxy-quinoxaline, not only reduces the discharge capacity of the solid waste, the protection of the environment, reduces the quizalofop-P-ethyl intermediate cost. (by machine translation)

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