Category: 32717-95-6

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer(SMILESS: C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5,cas:32717-95-6) is researched.Name: (S)-Propane-1,2-diamine dihydrochloride. The article 《Olefin-Supported Cationic Copper Catalysts for Photochemical Synthesis of Structurally Complex Cyclobutanes》 in relation to this compound, is published in Angewandte Chemie, International Edition. Let’s take a look at the latest research on this compound (cas:32717-95-6).

The sole method available for the photocycloaddition of unconjugated aliphatic alkenes is the Cu-catalyzed Salomon-Kochi reaction. The [Cu(OTf)]2·benzene catalyst that has been standard in this reaction for many decades, however, is air-sensitive, prone to photodecomposition, and poorly reactive towards sterically bulky alkene substrates. Using bench-stable precursors, an improved catalyst system with superior reactivity and photostability has been designed, and it offers significantly expanded substrate scope. The utility of this new catalyst for the preparation of sterically crowded cyclobutane structures is highlighted through the preparation of the cores of the natural products sulcatine G and perforatol.

Although many compounds look similar to this compound(32717-95-6)Product Details of 32717-95-6, numerous studies have shown that this compound(SMILES:C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

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Synthetic Route of C16H16Cl2Cu2. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Oxazepine Synthesis by Copper-Catalyzed Intermolecular Cascade Reactions between O-Propargylic Oximes and Dipolarophiles.

Oxazepines I [R1 = n-Pr, cyclohexyl, Ph, 4-F3CC6H4, 4-MeOC6H4; R2 = n-Pr, Me3SiCH2, Ph, 4-MeOC6H4, 4-F3CC6H4; R3 = H, 4-F3CC6H4; R5 = H, R4R6 = C(O)NR7C(O), R7 = H, Me, t-Bu, Ph, etc.; R4 = H, R5 = R6 = MeO2C, i-PrO2C; etc.] were efficiently prepared from O-propargylic oximes II and dipolarophiles R4R5C:CHR6 via copper-catalyzed cascade reactions which proceed through a 2,3-rearrangement, [3 + 2] cycloaddition, and subsequent 1,3-oxygen migration. The process involves the cleavage of C-O and N-O bonds.

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In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Lewis-Base Adducts of Group 11 Metal(I) Compounds. LXXV. Structural Systematics of the Binuclear Copper(I) Halide: 1,5-Cyclooctadiene (cod) 2:2 Adducts, [(cod)Cu(μ-X)2Cu(cod)], X = Cl, Br, I, published in 2004-09-30, which mentions a compound: 32717-95-6, Name is Chloro(1,5-cyclooctadiene)copper(I) dimer, Molecular C16H16Cl2Cu2, Safety of Chloro(1,5-cyclooctadiene)copper(I) dimer.

Adducts of 1,5-cyclooctadiene (cod) with the copper(I) halides, CuX (X = Cl, Br, I) of 1:1 stoichiometry are confirmed as binuclear species of [(cod)Cu(μ-X)2Cu(cod)] by single crystal x-ray studies, those for X = Cl, I being executed at low-temperature The study for X = Cl is a redetn., exposing disorder in one of the copper atom sites; a similar redetn. of [Cu(cod)2](ClO4) shows disorder in respect of one of the ligands. Bonding parameters are compared with those for other Lewis-base analogs.

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 32717-95-6, is researched, Molecular C16H16Cl2Cu2, about Complexes prepared from mercuric halides and dicopper di-μ-halobis(η-cycloocta-1,5-dienes), the main research direction is copper mercury cyclooctadiene halide; structure mercury copper cyclooctadiene.Computed Properties of C16H16Cl2Cu2.

Di-μ-halobis(η-1,5-cyclooctadiene)dicopper, prepared from CuX (X = Cl, Br) and 1,5-cyclooctadiene (COD), complexed with HgX2 (X = Cl, Br) to give [(CODCuX)nHgX2]m [X = Cl, n = 1 (I); X = Br, n = 2 (II)]. I crystallized in an orthorhombic system with Z = 8, a 7.19 (±3), b 17.03 (±2), c 19.64 (±3) Å. II formed monoclinic crystals with Z = 4, a 16.17 (±9), b 12.19 (±2), c 13.63 (±9) Å, β = 127°3′.

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Safety of Chloro(1,5-cyclooctadiene)copper(I) dimer. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Gold catalyzed rearrangements of strained small ring hydrocarbons. Author is Meyer, Lueder U.; de Meijere, Armin.

Diademane (I) underwent Au-catalyzed rearrangement to give 50% snoutene (II) together with 5% of the thermally rearranged product, triquinacene. At elevated temperatures, II underwent Au-catalyzed rearrangement to basketene (III), which subsequently thermally rearranged to Nenitzescu’s hydrocarbon. Similar catalysis of the diene IV, gave >90% tetrahydronaphthalene.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 32717-95-6, is researched, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2Journal, Journal of Organometallic Chemistry called Chemistry of copper(I) β-diketonate complexes. VI. Synthesis, characterization and chemical vapor deposition of 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione (fod) copper(I) (fod)CuL complexes and the solid state structure of (fod)Cu(PMe3), Author is Chi, K. M.; Corbitt, T. S.; Hampden-Smith, M. J.; Kodas, T. T.; Duesler, E. N., the main research direction is copper CVD; octanedione dimethylheptafluoro copper Lewis base complex; Lewis base dimethylheptafluorooctanedione copper complex; crystallog Lewis base dimethylheptafluorooctanedione copper complex.Recommanded Product: Chloro(1,5-cyclooctadiene)copper(I) dimer.

A series of copper(I) compounds of the general formula (fod)CuL, where fod = 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione, and L = PMe3, PEt3, 1,5-cyclooctadiene (1,5-COD), vinyltrimethylsilane (VTMS), 2-butyne, bis(trimethylsilyl)acetylene (BTMSA), have been prepared by the reaction of Na[fod] with CuCl in the presence of the appropriate amount of the Lewis base, L. All the compounds were characterized by elemental anal., 1H, 13C, 19F, 31P and IR spectroscopies. The spectroscopic data are consistent with the chelation of the β-diketonate ligand through its oxygen atoms to the copper(I) center. The anal. data are consistent with the empirical formula (fod)CuL. One compound, (fod)CuPMe3, was characterized in the solid-state by single-crystal x-ray diffraction which confirmed the empirical formula and revealed the monomeric nature of this species in the solid state. The distorted trigonal planar coordination environment observed for this species is common to these species. The Cu-O distances are significantly different within the limits of error on the data possibly as a result of inductive effects of the different β-diketonate substituents. Hot- and cold-wall chem. vapor deposition experiments revealed that these species are generally not suitable as precursors for the deposition of copper due to their low thermal stability. While pure copper films could be deposited, as determined by Auger electron spectroscopy, from the compounds (fod)CuL, where L = PMe3, 2-butyne and BTMSA, heating the precursors to increase their vapor pressures resulted in significant thermal decomposition in the source reservoir. As a result, deposition rates of only 100 Å/min were achieved. No selectivity was observed on W vs. SiO2 substrates under the conditions employed. The other compounds, (fod)CuL, where L = 1,5-COD, VTMS, were too thermally unstable for CVD experiments

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Gold catalyzed rearrangements of strained small ring hydrocarbons.Electric Literature of C16H16Cl2Cu2.

Diademane (I) underwent Au-catalyzed rearrangement to give 50% snoutene (II) together with 5% of the thermally rearranged product, triquinacene. At elevated temperatures, II underwent Au-catalyzed rearrangement to basketene (III), which subsequently thermally rearranged to Nenitzescu’s hydrocarbon. Similar catalysis of the diene IV, gave >90% tetrahydronaphthalene.

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Computed Properties of C16H16Cl2Cu2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Synthesis, structural characterization, and bonding analysis of two-coordinate copper(I) and silver(I) complexes of pyrrole-based bis(phosphinimine): new metal-pyrrole ring π-interactions. Author is Jha, Vikesh Kumar; Das, Sanghamitra; Subramaniyan, Vasudevan; Guchhait, Tapas; Dakua, Kishan Kumar; Mishra, Sabyashachi; Mani, Ganesan.

The reaction between 2,5-bis(diphenylphosphinomethyl)pyrrole and Me3SiN3 gave the new pyrrole-based bis(phosphinimine) L1H in an excellent yield. L1H reacts with [CuCl(COD)]2, AgBF4, or AgOTf to give the corresponding two-coordinate mononuclear ionic complex formulated as [M{(L1H)-κ2N,N}]+[X]- where M = Cu and Ag; X = [CuCl2], BF4 or OTf. Their single crystal x-ray diffraction studies confirmed the two-coordinate geometry formed by the chelate bonding mode of L1H. These 10-membered metalacycles exhibit planar chirality and were also characterized by spectroscopic methods. In addition, in all three structures, there exists a hitherto unknown π-interaction between the pyrrole ring atoms and metal, represented as η2-(Cα-N) in the copper(I) complex, and η3-(Cα-N-Cα’) in the silver(I) complexes. These weak interactions were supported by DFT calculations in terms of their electron densities, non-covalent interaction plots and the decrease in the aromaticity of the pyrrole ring.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 32717-95-6, is researched, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2Journal, Texas Journal of Science called Vinylmetallics as ligands. II. Reaction of (1,5-cyclooctadiene)copper(I) chloride with dimethyldivinylsilane and dibutyldivinyltin, Author is Fitch, John W.; Kettner, Charles A., the main research direction is vinylmetallic ligand; copper vinylmetallic complex stability; cyclooctadiene copper complex; silanedimethyldivinyl copper complex; tin dibutyldivinyl copper complex; stannane dibutyldivinyl copper complex; stability vinylmetallic complex.Application In Synthesis of Chloro(1,5-cyclooctadiene)copper(I) dimer.

The stability of Me2Si(CH:CH2).2CuCl and Bu2Sn(CH:CH2)2.2CuCl was compared to that of 1,5-cyclooctadiene-CuCl. Both ligand exchange reactions and competition reactions favored the formation of the vinylmetallic complexes over formation of 1,5-cyclooctadiene-CuCl.

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Iglesias, M.; Gomez-Lor, B.; Santos, A. published the article 《Copper(I) complexes with the hexaazafulleroid C60(NR)6, derived from (2S,4S)-4-azido-1-benzyloxycarbonyl-2-(t-butylaminocarbonyl)pyrrolidine as multitopic ligand. Catalytic properties in oxidation of sulfides》. Keywords: copper hexaazafulleroid pyrrolidinecarboxamide preparation sulfide oxidation catalyst; pyrrolidinecarboxylate hexaazafulleroid copper preparation sulfide oxidation catalyst; azafulleroid pyrrolidinecarboxamide copper preparation sulfide oxidation catalyst; fulleroid pyrrolidinecarboxamide copper preparation sulfide oxidation catalyst; fullerene pyrrolidinecarboxamide copper preparation sulfide oxidation catalyst.They researched the compound: Chloro(1,5-cyclooctadiene)copper(I) dimer( cas:32717-95-6 ).Computed Properties of C16H16Cl2Cu2. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:32717-95-6) here.

Reactions in a molar ratio 1:6 of the hexaazafulleroid C60(NR)6 (1), derived from the chiral azide (2S,4S)-4-azido-1-benzyloxycarbonyl-2-(t-butylaminocarbonyl)pyrrolidine (2), with the copper(I) complexes [Cu(MeCN)4]ClO4 and [CuCl(cod)]2 (cod = 1,5-cyclooctadiene) lead to the polymetalated species C60[(NR)Cu(MeCN)2(ClO4)]6 (3) and C60[(NR)CuCl(cod)]6·2CuCl (4), resp., which were characterized by IR, 1H- and 13C-NMR spectroscopies and by mass spectrometry techniques (ES-, FAB- and MALDI-MS). The performance of both complexes as catalysts in the oxidation of alkyl Ph sulfides [methyl Ph sulfide, (2-ethylbutyl) Ph sulfide] was evaluated.

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