Category: 32717-95-6

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya called Liquid-phase oxidation of transition metals. 3. Direct synthesis of chelate complexes of Group IA and VIII metals, Author is Kurskov, S. N.; Ivleva, I. N.; Lavrent’ev, I. P.; Khidekel, M. L., which mentions a compound: 32717-95-6, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2, COA of Formula: C16H16Cl2Cu2.

The reactions of Co, Ni, and Cu were studied with organic systems, containing a chelating ligand, the introduction of which into the organic system permits the synthesis of new complexes. Thus, CoL(acac)2 (L = α,α’-dipyridyl (I), γ,γ’-dipyridyl, Hacac = acetylacetone), H[CoCl2(DMG)2] (HDMG = dimethylglyoxime), CoQ2(H2O)2 (HQ = 8-hydroxyquinoline), NiL(acac)2 (L = I), NiLCl2 (L = I), NiCl2(Me2SO)3(HDMG), Ni(DMG)2, NiCl2(HDMG)2Z (Z = dimethylacetamide), [Cu(COD)Cl]2 (COD = 1,5-cyclooctadiene), CuCl2(HDMG)Z, CuCl2(HDMG), [CuCl2(HDMG)]2Me2SO, CuLCl2 (L = I), Cu(DMG)2, and Cu(acac)2.

There is still a lot of research devoted to this compound(SMILES：C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5)COA of Formula: C16H16Cl2Cu2, and with the development of science, more effects of this compound(32717-95-6) can be discovered.

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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Chemical Science called An N-heterocyclic carbene ligand promotes highly selective alkyne semihydrogenation with copper nanoparticles supported on passivated silica, Author is Kaeffer, Nicolas; Liu, Hsueh-Ju; Lo, Hung-Kun; Fedorov, Alexey; Coperet, Christophe, which mentions a compound: 32717-95-6, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2, Name: Chloro(1,5-cyclooctadiene)copper(I) dimer.

A surface organometallic route that generates copper nanoparticles (NPs) on a silica support while simultaneously passivating the silica surface with trimethylsiloxy groups is reported. The material was active for the catalytic semihydrogenation of phenylalkyl, dialkyl and diaryl alkynes and displayed high chemo- and stereoselectivity at full alkyne conversion to corresponding (Z)-olefins in the presence of an N-heterocyclic carbene (NHC) ligand. Solid-state NMR spectroscopy using the NHC ligand 13C-labeled at the carbenic carbon revealed a genuine coordination of the carbene to Cu NPs. The presence of distinct Cu surface environments and the coordination of the NHC to specific Cu sites likely accounted for the increased selectivity.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 32717-95-6, is researched, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2Journal, Journal of Organometallic Chemistry called Copper(I) complexes with the hexaazafulleroid C60(NR)6, derived from (2S,4S)-4-azido-1-benzyloxycarbonyl-2-(t-butylaminocarbonyl)pyrrolidine as multitopic ligand. Catalytic properties in oxidation of sulfides, Author is Iglesias, M.; Gomez-Lor, B.; Santos, A., the main research direction is copper hexaazafulleroid pyrrolidinecarboxamide preparation sulfide oxidation catalyst; pyrrolidinecarboxylate hexaazafulleroid copper preparation sulfide oxidation catalyst; azafulleroid pyrrolidinecarboxamide copper preparation sulfide oxidation catalyst; fulleroid pyrrolidinecarboxamide copper preparation sulfide oxidation catalyst; fullerene pyrrolidinecarboxamide copper preparation sulfide oxidation catalyst.Electric Literature of C16H16Cl2Cu2.

Reactions in a molar ratio 1:6 of the hexaazafulleroid C60(NR)6 (1), derived from the chiral azide (2S,4S)-4-azido-1-benzyloxycarbonyl-2-(t-butylaminocarbonyl)pyrrolidine (2), with the copper(I) complexes [Cu(MeCN)4]ClO4 and [CuCl(cod)]2 (cod = 1,5-cyclooctadiene) lead to the polymetalated species C60[(NR)Cu(MeCN)2(ClO4)]6 (3) and C60[(NR)CuCl(cod)]6·2CuCl (4), resp., which were characterized by IR, 1H- and 13C-NMR spectroscopies and by mass spectrometry techniques (ES-, FAB- and MALDI-MS). The performance of both complexes as catalysts in the oxidation of alkyl Ph sulfides [methyl Ph sulfide, (2-ethylbutyl) Ph sulfide] was evaluated.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 32717-95-6, is researched, SMILESS is C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5, Molecular C16H16Cl2Cu2Journal, Article, Angewandte Chemie, International Edition called Oxazepine Synthesis by Copper-Catalyzed Intermolecular Cascade Reactions between O-Propargylic Oximes and Dipolarophiles, Author is Nakamura, Itaru; Kudo, Yu; Terada, Masahiro, the main research direction is oxime propargylic diastereoselective cascade dipolarophile copper catalyst; oxazepine alkylidene diastereoselective synthesis; copper; cycloaddition; heterocycles; rearrangement; synthetic methods.Reference of Chloro(1,5-cyclooctadiene)copper(I) dimer.

Oxazepines I [R1 = n-Pr, cyclohexyl, Ph, 4-F3CC6H4, 4-MeOC6H4; R2 = n-Pr, Me3SiCH2, Ph, 4-MeOC6H4, 4-F3CC6H4; R3 = H, 4-F3CC6H4; R5 = H, R4R6 = C(O)NR7C(O), R7 = H, Me, t-Bu, Ph, etc.; R4 = H, R5 = R6 = MeO2C, i-PrO2C; etc.] were efficiently prepared from O-propargylic oximes II and dipolarophiles R4R5C:CHR6 via copper-catalyzed cascade reactions which proceed through a 2,3-rearrangement, [3 + 2] cycloaddition, and subsequent 1,3-oxygen migration. The process involves the cleavage of C-O and N-O bonds.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Oxazepine Synthesis by Copper-Catalyzed Intermolecular Cascade Reactions between O-Propargylic Oximes and Dipolarophiles.Name: Chloro(1,5-cyclooctadiene)copper(I) dimer.

Oxazepines I [R1 = n-Pr, cyclohexyl, Ph, 4-F3CC6H4, 4-MeOC6H4; R2 = n-Pr, Me3SiCH2, Ph, 4-MeOC6H4, 4-F3CC6H4; R3 = H, 4-F3CC6H4; R5 = H, R4R6 = C(O)NR7C(O), R7 = H, Me, t-Bu, Ph, etc.; R4 = H, R5 = R6 = MeO2C, i-PrO2C; etc.] were efficiently prepared from O-propargylic oximes II and dipolarophiles R4R5C:CHR6 via copper-catalyzed cascade reactions which proceed through a 2,3-rearrangement, [3 + 2] cycloaddition, and subsequent 1,3-oxygen migration. The process involves the cleavage of C-O and N-O bonds.

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Related Products of 32717-95-6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Vibrational spectra of 1,5-cyclooctadiene, di-μ-chlorobis[(1,5-cyclooctadiene)rhodium(I)], di-μ-chlorobis[(1,5-cyclooctadiene)copper(I)] and bis(1,5-cyclooctadiene)copper(I) perchlorate. Author is Barna, Gabriel G.; Butler, Ian S..

The vibrational spectra of 1,5-cyclooctadiene (C8H12, COD) and the Rh(I) and Cu(I) complexes, [(COD)RhCl]2, [(COD)CuCl]2 and (COD)2CuClO4, were investigated. In the liquid state, COD exists in a C2v “”tub”” configuration; the same structure is apparently also preserved in the solid at -196°. The spectra of the dimeric complexes are in accord with the known D2h mol. symmetries and assignments for the ν(C:C), ν(M-Cl) and ν(M-olefin) vibrations are proposed accordingly. The spectra of (COD)2CuClO4 indicate the presence of a non-bonded olefinic group and a 3-coordinate structure is proposed for the (COD)2Cu+ ion.

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Chi, K. M.; Corbitt, T. S.; Hampden-Smith, M. J.; Kodas, T. T.; Duesler, E. N. published the article 《Chemistry of copper(I) β-diketonate complexes. VI. Synthesis, characterization and chemical vapor deposition of 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione (fod) copper(I) (fod)CuL complexes and the solid state structure of (fod)Cu(PMe3)》. Keywords: copper CVD; octanedione dimethylheptafluoro copper Lewis base complex; Lewis base dimethylheptafluorooctanedione copper complex; crystallog Lewis base dimethylheptafluorooctanedione copper complex.They researched the compound: Chloro(1,5-cyclooctadiene)copper(I) dimer( cas:32717-95-6 ).COA of Formula: C16H16Cl2Cu2. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:32717-95-6) here.

A series of copper(I) compounds of the general formula (fod)CuL, where fod = 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione, and L = PMe3, PEt3, 1,5-cyclooctadiene (1,5-COD), vinyltrimethylsilane (VTMS), 2-butyne, bis(trimethylsilyl)acetylene (BTMSA), have been prepared by the reaction of Na[fod] with CuCl in the presence of the appropriate amount of the Lewis base, L. All the compounds were characterized by elemental anal., 1H, 13C, 19F, 31P and IR spectroscopies. The spectroscopic data are consistent with the chelation of the β-diketonate ligand through its oxygen atoms to the copper(I) center. The anal. data are consistent with the empirical formula (fod)CuL. One compound, (fod)CuPMe3, was characterized in the solid-state by single-crystal x-ray diffraction which confirmed the empirical formula and revealed the monomeric nature of this species in the solid state. The distorted trigonal planar coordination environment observed for this species is common to these species. The Cu-O distances are significantly different within the limits of error on the data possibly as a result of inductive effects of the different β-diketonate substituents. Hot- and cold-wall chem. vapor deposition experiments revealed that these species are generally not suitable as precursors for the deposition of copper due to their low thermal stability. While pure copper films could be deposited, as determined by Auger electron spectroscopy, from the compounds (fod)CuL, where L = PMe3, 2-butyne and BTMSA, heating the precursors to increase their vapor pressures resulted in significant thermal decomposition in the source reservoir. As a result, deposition rates of only 100 Å/min were achieved. No selectivity was observed on W vs. SiO2 substrates under the conditions employed. The other compounds, (fod)CuL, where L = 1,5-COD, VTMS, were too thermally unstable for CVD experiments

From this literature《Chemistry of copper(I) β-diketonate complexes. VI. Synthesis, characterization and chemical vapor deposition of 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione (fod) copper(I) (fod)CuL complexes and the solid state structure of (fod)Cu(PMe3)》,we know some information about this compound(32717-95-6)COA of Formula: C16H16Cl2Cu2, but this is not all information, there are many literatures related to this compound(32717-95-6).

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Catalytic properties of precious metal complexes: carbonylation of methanol to acetic acid in the presence of iridium compounds.Synthetic Route of C16H16Cl2Cu2.

No major difference was found between Rh- and Ir-catalyzed homogeneous carbonylation of MeOH to HOAc, using MeI as promoter. The dependence of the activity on the nature of the Ir based catalyst is greater than that of th Rh-based catalyst, and the maximum activity occurs at different conditions. Rh(CO)2I2- and Ir(CO)2I2- are the catalytic species in these reactions and the Ir complexes are the best catalysts of all the Pt metal complexes. The mechanism of the reaction is discussed.

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 32717-95-6, is researched, Molecular C16H16Cl2Cu2, about Asymmetric [4 + 3] Annulations for Constructing Divergent Oxepane Frameworks via Cooperative Tertiary Amine/Transition Metal Catalysis, the main research direction is oxepane framework preparation enantioselective diastereoselective; indole vinyl carbonate amine metal catalyst annulation.Recommanded Product: 32717-95-6.

Asym. [4+3] annulations between isatin-derived Morita-Baylis-Hillman carbonates and two types of vinyl carbonates synergistically catalyzed by tertiary amines and transition metals, through chemoselective assemblies of in situ formed allylic ylides and metal-containing 1,4-dipoles were reported. A range of oxepane frameworks I [R1 = H, 5-Me, 5-Br, etc.; R2 = Me, Et; R3 = Me, allyl, Bn, etc.] and II [X = CF, CCH3, NH, etc.] were generally constructed in moderate to good yields with high stereocontrol. Moreover, all four diastereomers for the products bearing vicinal stereocenters were accessible by tuning tertiary amine and metal catalysts.

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The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer( cas:32717-95-6 ) is researched.Electric Literature of C16H16Cl2Cu2.Meyer, Lueder U.; de Meijere, Armin published the article 《Gold catalyzed rearrangements of strained small ring hydrocarbons》 about this compound( cas:32717-95-6 ) in Tetrahedron Letters. Keywords: polycycloalkane gold catalysis rearrangement; small ring hydrocarbon rearrangement. Let’s learn more about this compound (cas:32717-95-6).

Diademane (I) underwent Au-catalyzed rearrangement to give 50% snoutene (II) together with 5% of the thermally rearranged product, triquinacene. At elevated temperatures, II underwent Au-catalyzed rearrangement to basketene (III), which subsequently thermally rearranged to Nenitzescu’s hydrocarbon. Similar catalysis of the diene IV, gave >90% tetrahydronaphthalene.

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