Category: quinoxaline

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 8-Hydroxyquinoline 1-oxide(SMILESS: OC1=CC=CC2=CC=C[N+]([O-])=C12,cas:1127-45-3) is researched.Reference of 1-(Bromomethyl)-4-ethylbenzene. The article 《Effects of substituents on the intramolecular hydrogen bond in 8-quinolinol-N-oxides》 in relation to this compound, is published in Journal of the Indian Chemical Society. Let’s take a look at the latest research on this compound (cas:1127-45-3).

IR spectral and deuteration studies on 8-quinolinol-N-oxides and its 5-nitro-, 5-nitroso-, 5-amino-, 5-phenylazo-, 5,7-dibromo- and 5,7-diiodo-derivatives in solid and in solution state confirm the presence of a strong intramol. unsym. H bond involving the hydroxyl hydrogen atom and the N-oxide oxygen atom. The structure of the complex absorption pattern in the region 2850 cm-1-1800 cm-1 is explained in terms of Fermi resonance interaction between the νOH of O-H…O and the overtone and combination bands of (δOH + νC-O) and other fundamental vibrations of the mol. The absence of any significant absorptions in the νOH region in the spectra of 5,7-dichloro- and 5,7-dinitro-derivatives coupled with strong and broad absorption in 1500 cm-1-600 cm-1 region is perhaps due to the presence of very short hydrogen bonds in these compounds

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The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《On prediction of OH stretching frequencies in intramolecularly hydrogen bonded systems》. Authors are Hansen, Poul Erik; Spanget-Larsen, Jens.The article about the compound:8-Hydroxyquinoline 1-oxidecas:1127-45-3,SMILESS:OC1=CC=CC2=CC=C[N+]([O-])=C12).Category: quinoxaline. Through the article, more information about this compound (cas:1127-45-3) is conveyed.

OH stretching frequencies are investigated for a series of non-tautomerizing systems with intramol. hydrogen bonds. Effective OH stretching wavenumbers are predicted by the application of empirical correlation procedures based on the results of B3LYP/6-31G(d) theor. calculations in the harmonic and PT2 anharmonic approximations, as well as on exptl. NMR parameters, i.e., proton chem. shifts (δ H) and two-bond deuterium isotope effects on 13C chem. shifts (2ΔCOD). The procedures are applied in a discussion of the spectra of 2,6-dihydroxy-4-methylbenzaldehyde and 8-hydroxyquinoline N-oxide. The spectrum of the former displays a broad, composite band between 3500 and 2500 cm-1 which can be assigned to overlapping monomer and dimer contributions. In the latter case, the results support a reassignment of the OH stretching band of 8-hydroxyquinoline N-oxide; the reassignment is supported by correlation with the IR spectra of a series of substituted derivatives

Although many compounds look similar to this compound(1127-45-3)Category: quinoxaline, numerous studies have shown that this compound(SMILES:OC1=CC=CC2=CC=C[N+]([O-])=C12), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

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In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Oxidation of 1-naphthol and related phenols with hydrogen peroxide and potassium superoxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides in different reaction conditions, published in 1999-01-08, which mentions a compound: 1127-45-3, Name is 8-Hydroxyquinoline 1-oxide, Molecular C9H7NO2, Application In Synthesis of 8-Hydroxyquinoline 1-oxide.

Reaction of 1-naphthol and related phenols with hydrogen peroxide catalyzed by 5,10,15,20-tetra(pentafluorophenyl)porphyrinatoiron(III) chloride gives quinones and oxidative coupling products, whereas the reaction of naphthols with hydrogen peroxide catalyzed by 5,10,15,20-tetramesitylporphyrinatoiron(III) chloride gives the above products along with quinone epoxides in moderate yields. The reaction of quinone with potassium superoxide catalyzed by Me12TPPFe(III)Cl and p-MeOTPPFe(III)Cl give higher yields of quinone epoxides than the reaction of quinone with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides.

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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider

Synthetic Route of C16H16Cl2Cu2. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Chloro(1,5-cyclooctadiene)copper(I) dimer, is researched, Molecular C16H16Cl2Cu2, CAS is 32717-95-6, about Oxazepine Synthesis by Copper-Catalyzed Intermolecular Cascade Reactions between O-Propargylic Oximes and Dipolarophiles.

Oxazepines I [R1 = n-Pr, cyclohexyl, Ph, 4-F3CC6H4, 4-MeOC6H4; R2 = n-Pr, Me3SiCH2, Ph, 4-MeOC6H4, 4-F3CC6H4; R3 = H, 4-F3CC6H4; R5 = H, R4R6 = C(O)NR7C(O), R7 = H, Me, t-Bu, Ph, etc.; R4 = H, R5 = R6 = MeO2C, i-PrO2C; etc.] were efficiently prepared from O-propargylic oximes II and dipolarophiles R4R5C:CHR6 via copper-catalyzed cascade reactions which proceed through a 2,3-rearrangement, [3 + 2] cycloaddition, and subsequent 1,3-oxygen migration. The process involves the cleavage of C-O and N-O bonds.

Although many compounds look similar to this compound(32717-95-6)Synthetic Route of C16H16Cl2Cu2, numerous studies have shown that this compound(SMILES:C12=C(CCC3=C4CC2)[Cu+]1534[Cl-][Cu+]678(C9=C6CCC7=C8CC9)[Cl-]5), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

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Quinoxaline – Wikipedia,
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Fujimoto, Hayato; Kusano, Momoka; Kodama, Takuya; Tobisu, Mamoru published an article about the compound: (R)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine( cas:221012-82-4,SMILESS:COC(C=C1P(C2=CC=CC=C2)C3=CC=CC=C3)=NC(OC)=C1C4=C(OC)N=C(OC)C=C4P(C5=CC=CC=C5)C6=CC=CC=C6 ).Quality Control of (R)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:221012-82-4) through the article.

The Ni-catalyzed cyclization of bisphosphine derivatives to form various phosphacycles is reported. The reaction proceeds via the cleavage of two C-P bonds of the bisphosphine. Unlike the previously reported Pd catalysts, the use of Ni as a catalyst allows for the cyclization that requires C(alkyl)-P bond cleavage. A phospha-nickelacycle intermediate was successfully isolated and characterized by x-ray crystallog.

Although many compounds look similar to this compound(221012-82-4)Quality Control of (R)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine, numerous studies have shown that this compound(SMILES:COC(C=C1P(C2=CC=CC=C2)C3=CC=CC=C3)=NC(OC)=C1C4=C(OC)N=C(OC)C=C4P(C5=CC=CC=C5)C6=CC=CC=C6), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider

Quality Control of 8-Hydroxyquinoline 1-oxide. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 8-Hydroxyquinoline 1-oxide, is researched, Molecular C9H7NO2, CAS is 1127-45-3, about Magnetic study of a one-dimensional Mn(II) coordination polymer dealing with π-π stacking.

A new one-dimensional chain manganese(II) coordination polymer, {[Mn(μ-Dpd)(Q)2(H2O)2]2(ClO4)}n (Dpd = 2,5-dimethylpyrazine-1,4-dioxide; Q = 8-hydroxylquinoline N-oxide), was synthesized with 2,5-dimethylpyrazine-1,4-dioxide as bridge ligand and 8-hydroxylquinoline N-oxide as terminal ligand, and its crystal structure determined by X-ray crystallog. The structure anal. indicates that there are two pathways for magnetic interactions: one is through bridge ligand 2,5-dimethylpyrazine-1,4-dioxide, and another is by π-π stacking of adjacent quinoline rings. The theor. calculations reveal that there exist a anti-ferromagnetic interaction from spin delocalization and a ferromagnetic interaction from spin polarization for 2,5-dimethylpyrazine-1,4-dioxide bridge pathway, but the anti-ferromagnetic interaction is stronger than the ferromagnetic interaction leading to an anti-ferromagnetic interaction with J = -2.53 cm-1, whereas for the π-π stacking pathway it resulted in a ferromagnetic interaction with J = 0.013 cm-1. The exptl. fitting on the data of the variable temperature magnetic susceptibilities gave the magnetic interaction constant J = 0.07 cm-1, which is similar with the results of the theor. calculations

Although many compounds look similar to this compound(1127-45-3)Quality Control of 8-Hydroxyquinoline 1-oxide, numerous studies have shown that this compound(SMILES:OC1=CC=CC2=CC=C[N+]([O-])=C12), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 8-Hydroxyquinoline 1-oxide, is researched, Molecular C9H7NO2, CAS is 1127-45-3, about The oxidation of pyridines catalyzed by surfactant-encapsulated polyoxometalate [(C18H37)2(CH3)2N]8[HBW11O39] with the temperature-responsive property of solubility, the main research direction is oxidation pyridine catalyzed surfactant encapsulated polyoxometalate solubility.Name: 8-Hydroxyquinoline 1-oxide.

Temperature-responsive characterization of solubility based on a surfactant-encapsulated polyoxometalate ([(C18H37)2(CH3)2N]8[HBW11O39]) in tert-Bu alc. was described and used in catalytic oxidation of pyridines. The catalyst could be recovered and reused several times by controlling the temperature

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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Tripodal 4-Pyridyl-Derived Host Ligands and Their Metallo-Supramolecular Chemistry: Stella Octangula and Bowl-Shaped Assemblies, published in 2010-01-18, which mentions a compound: 217192-22-8, mainly applied to palladium cyclotriveratrylene derivative preparation bowl shaped assembly; crystal structure cyclotriveratrylene cyclotriguaiacylene derivative palladium complex, Recommanded Product: (4-(Pyridin-4-yl)phenyl)methanol.

The synthesis of five new cyclotriveratrylene derivatives with 4-pyridyl side arms is reported, along with the crystal structures of three of these. Three ligands with extended 4-pyridylphenyl side arms and a ligand derived from cyclotriphenolene form [Pd6L8]12+ stella octangula assemblies using diffusion-ordered spectroscopy NMR and electrospray MS techniques. This confirms the generality of the stella octangula assembly, providing that the ligand arms show a degree of rigidity. The more flexible ether-linked ligand tris(4-pyridylmethyl)cyclotriguaiacylene forms a smaller [Pd3L4]6+ bowl-shaped assembly in the solid state and in solution The previously reported ligand tris(4-pyridylmethylamino)cyclotriguaiacylene forms a similar assembly in solution

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Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Nuclear magnetic resonance study of some paramagnetic hydrated fluorides》. Authors are Easwaran, K. R. K.; Srinivasan, R..The article about the compound:Nickel(ii)fluoridetetrahydratecas:13940-83-5,SMILESS:[H]O[H].[H]O[H].[H]O[H].[H]O[H].[Ni+2].[F-].[F-]).Recommanded Product: 13940-83-5. Through the article, more information about this compound (cas:13940-83-5) is conveyed.

A preliminary study of 1H and 19F in compounds of the type MF2.4H2O (M = Mn, Fe, Co, Ni, Zn) was carried out (at room temperature and 90°K.), to investigate the nature of the hyperfine interaction. The samples were prepared by dissolving the carbonates (except in the case of Fe, where pure Fe powder was used) in 40% HF and precipitating with EtOH. The Fe compound was not very stable, and was kept in vacuo. X-ray powder photographs revealed the Fe, Co, Ni, and Zn salts to be isomorphous. For the 1H resonance, an increase in line width at low temperatures is attributed to the increase in the electronic polarization. The 19F fractional shift, α, increased through the Ni++, Co++, Fe++ series (increasing number of unpaired spins) at room temperature This order was not preserved at lower temperatures Paramagnetic susceptibilities were also measured at room temperature by the Gouy method.

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Quinoxaline – Wikipedia,
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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: (R)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine, is researched, Molecular C38H34N2O4P2, CAS is 221012-82-4, about Polyethylene glycol as an environmentally friendly and recyclable reaction medium for enantioselective hydrogenation.Recommanded Product: (R)-2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine.

Polyethylene glycol (PEG) was found to be an inexpensive, non-toxic and recyclable reaction medium for ruthenium- and rhodium-catalyzed asym. hydrogenation of 2-arylacrylic acids (Ru-catalyzed C=C bond reduction), enamides (Rh-catalyzed C=C bond reduction), β-keto esters and simple aromatic ketones (Ru-catalyzed C=O bond reduction). In all cases, high catalytic activities and enantioselectivities have been achieved, which are comparable to those obtained in conventional organic solvent systems. The Ru and Rh catalysts prepared with com. available chiral diphosphine ligands could be readily recycled by simple extraction, as in the case of ionic liquids, and reused up to nine times without obvious loss of catalytic activity and enantioselectivity. The reduced products were obtained from the extracts in high isolated yields. These results indicate that PEGs as new reaction media are attractive alternatives to room temperature ionic liquids

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Reference:
Quinoxaline – Wikipedia,
Quinoxaline | C8H6N2 | ChemSpider